Why Boat and RV Fiberglass Gelcoat Fades
by: Bill Rice
There are
probably a million and one temporary band-aid solutions
to the problem of appearance restoration and maintenance on
faded, dull, chalky. oxidized, discolored or sun weathered
boats fiberglass gelcoat or filon panels used in the RV and
truck siding markets. Vivilon is not one of those products
because our concern is with long term appearance
restoration and maintenance. Gelcoat restoration or
refurbishment is very similar to paint restoration or
rejuvenation in that the objective of both is the
restoration of like new, original color and gloss, shine and
luster to the gelcoat or paint surface. Taking a dull,
chalky, sun weathered, discolored, faded or oxidized surface
and restoring it to the color and luster it had when it was
new is just a matter of the using the proper applied
chemistry. Read the next paragraphs and you will learn why
fiberglass gelcoat fades or yellows and how to achieve lasting gelcoat or
paint restoration on any fiberglass gelcoat surface.
There are
probably a million and one temporary band-aid solutions
to the problem of appearance restoration and maintenance on
faded, dull, chalky. oxidized, discolored or sun weathered
boats fiberglass gelcoat or filon panels used in the RV and
truck siding markets. Vivilon is not one of those products
because our concern is with long term appearance
restoration and maintenance. Gelcoat restoration or
refurbishment is very similar to paint restoration or
rejuvenation in that the objective of both is the
restoration of like new, original color and gloss, shine and
luster to the gelcoat or paint surface. Taking a dull,
chalky, sun weathered, discolored, faded or oxidized surface
and restoring it to the color and luster it had when it was
new is just a matter of the using the proper applied
chemistry. Read the next paragraphs and you will learn why
fiberglass gelcoat fades or yellows and how to achieve lasting gelcoat or
paint restoration on any fiberglass gelcoat surface.
Let's be
clear, until recently, ALL fiberglass gelcoat was a
uniformly poor material to expose to the sun. One leading
supplier of polyester resins used in gelcoat said it this
way:
"The ability of composite materials to penetrate into
business sectors dominated by other construction materials
has been limited by a cost-effective means of achieving
acceptable performance characteristics with current gel coat
technologies. In many cases, the limiting factor has been
the gel coats ability to retain its original color and gloss
upon continual ultraviolet exposure as compared to the
performance of alternate coating technologies."
Now, there
are polyester gelcoat resins available that do a better job
of protecting color and gloss from the sun's radiation. Some
boat builders pay the price to have these better gelcoat
materials. Most do not. Read below for more information on
why this choice in gelcoat materials is important.
There is
only a slight difference between the fiberglass gelcoat of
boats (and other water craft) and the gelcoat of reinforced
polyester fiberglass panels (RFP, sometimes called
Reinforced Fiberglass Plastic) Trade named, Filon. Filon is
used as exterior siding on almost all fiberglass motorhomes,
travel trailer, campers and other RV's. The first difference
is in how fiberglass gelcoat is use in the manufacture of
boats versus RV's.
A
fiberglass gelcoat boat is made with a polished mirror
quality mold with is waxed with a mold release agent and
into which gelcoat is sprayed. The fiberglass gelcoat
polymer used is polyester gelcoat with a styrene diluent to
thin the viscosity of the polyester gelcoat and add to the
reactivity of the gelcoat blend. The gelcoat is reacted or
hardened with methyl ethyl ketone peroxide and let
cure.There is one optional step which is taken next by
quality fiberglass boat builders. A barrier coat of vinyl
ester is sprayed waterline to waterline to prevent osmosis
blistering in the fiberglass gelcoat. Possibly, another coat
of vinyl ester barrier coat is sprayed in for fiberglass
print resistance of the boat. The boat's fiberglass gelcoat
will have no imperfections if these steps are taken in the
boat building process. Obviously, these extra barrier coats
add time and expense to the making of a quality fiberglass
gelcoat hull; but, they are worth it.
The
gelcoat color coat is anywhere from 14-25 mils thick without
the barrier coat. This compares with a color coat on paint
of less than one mil with a clearcoat of
1.5-2 mills for a
car. Which brings up the subject of why don't fiberglass
boat builders use a clear gelcoat just like auto
manufacturers? Unfortunately, the chemistry of polyester
gelcoat won't work with a clearcoat like paint clearcoat
does. A fiberglass gelcoat boat with a clearcoat will have a
haze and develop a yellow appearance to the gelcoat,
especially on white or lighter color gelcoats. This problem
with clear gelcoat on fiberglass boats is substantially
worse than the yellowing problem caused with color gelcoat
on boats. The color gelcoat still is visibly effected by the
the sun. The sun's UV radiation attacks the aromatic monomer
in the polyester gelcoat's molecular structure. An aromatic
molecule is notorious for the light sensitivity it has in
comparison with more stable aliphatic molecules. Which is
why paints used in automotive coatings are ALWAYS aliphatic.
For example, the spray in bed liners business popularized by
Rhino Linings was infamous for rapid fade of their coatings.
This was because of the aromatic urethanes they used. The
aromatics were VASTLY cheaper (about a third the price of
aliphatic. Because the thickness of the liners, they used a
LOT of urethane. The price was right but the performance, as
far as sun fading resistance, was wrong.
Fiberglass
gelcoats, for both boats and RV's, start off with this
significant double disadvantage over automotive paint.
Fiberglass gelcoat manufactures of boats & RV's can't use
clear gelcoat and the color gelcoat they use prematurely
yellows, particularly on whites, Which is why most
fiberglass repair body shops use automotive paints when
refinishing a new part on boats and especially on RV gelcoat
Filon panels. Recently, polyester gelcoats have been
formulated with less aromatic content and with UV absorbers
and UV light stabilizers. These gelcoat polymers costs a lot
more money. Quality fiberglass boat builders buy them to
make their gelcoats perform better in sun light. The other
fiberglass boat builders produce cheaper but more sunlight
sensitive gelcoats. The saying, you get what you pay for, applies in fiberglass boat gelcoat like anything else.
After the
fiberglass gelcoat is cured, different types and grades of
fiberglass is applied to the gelcoat and bonded to give the
boat structural integrity. The fiberglass boat is then cured
and "popped" out of the boat's mold. The gelcoat that went
in first is now the boat's outermost surface. The quality
difference between fiberglass boats starts with the kind of
gelcoat material they use, whether a barrier or two barrier
coats are applied before fiberglass is laid, whether the
fiberglass boat is cored and with what, and the time the
gelcoat is allowed to cure in the boat's mold.
With Filon
panels, manufacture is a continuous process of gelcoat
resin(s) being reinforced with fiberglass to produce a panel
that has a very shiny and smooth surface on the outside and
a somewhat rough inside surface ready for bonding to the
frame structure of the RV. Filon is made by Kemlite, which
owns the trademark on the fiberglass panels. Their
smoothest, shiny, gloss finish is called the Medallion.
Extra gelcoat is applied during manufacture to assure
maximum gloss. Even though they are basically the only
manufacturer of fiberglass panels, and use better gelcoat
material with UV light absorbers and stabilizers, they
STILL fade. They admit fiberglass gelcoat panels fade most
dramatically during the first few years. Rapid fade is true
of ALL gelcoat not just fiberglass Filon panels.
To
understand how we restore or rejuvenate a like new color
appearance and shine to faded surfaces on fiberglass gelcoat,
it is necessary to examine the process by which paint fades,
because gelcoat, fades or degrades in the same way. Our
article on Why Paints Fade
explains the process in some detail. Here we'll explain some
further considerations that apply to paint; but, also impact
sun fading on fiberglass gelcoat as well.
The first
factor that effects the sun's UV radiation ability to impact
color retention, luster or gloss on a painted or gelcoat
surface, is the gelcoats
surface profile.
This is simply, when looked at on a microscopic level, how
smooth or rough the gelcoat surface is. The rougher it is,
the more peaks and valleys there will be in the gelcoat.
These peaks and valleys expose more surface to the sun's
radiant energy than a smooth surface would. Also, the peaks
of the gelcoat are only a few molecules wide, exposing them
to more rapid photo-oxidation (sunlight induced damage) than
the valleys. And, the valleys provide an excellent place for
all types of airborne or waterborne pollutants to collect
and further weaken the molecular bonds of the paint or
gelcoat. Of course, compounding, polishing or using a glaze
with some abrasive wears down and flattens those peaks and
valleys making a smoother gelcoat surface profile. That's
one band-aid way to solve that gelcoat problem short term.
The second
factor is
surface reactivity
or how the paint or gelcoat interacts with other materials.
Chemically inert (non-reactive)
paint or gelcoat surfaces interact far less with the
environment and therefore are subject to far slower UV
induced degradation of their color, gloss and luster. To put
it simply, for either paint or gelcoat, high energy is BAD;
low energy is GOOD. The way chemists express this is in the
dynes/centimeter number of a surface, or how slick it is.
Low numbers are better. Water has a surface tension at room
temperature of 73 dynes/centimeter. But, its surface tension
goes down dramatically as the temperature rises. The reason
HOT water is a much better cleaning solution than cold water
is simply that the lower surface tension of hot water allows
it to penetrate into and lift grime away better. Adding
dishwashing detergent adds surfactants (sur-face
act-ive
ag-ents)
that make it even lower surface tension. Something very
slick, like silicone, for instance, is an extremely low 24
dynes/centimeter. And, pure Teflon is 18. For comparison,
alkyd enamel, polyester, epoxy or polyurethane is 42-45
dynes/cm. On gelcoat or paint it is vitally important to get
the lowest surface tension possible. Guess how low Vivilon
takes it?
One
measure of this surface reactivity on fiberglass gelcoat or
paint, is the paint's or gelcoat's
surface energy. A simple way to express this concept of surface energy is
with how water flows over the surface of the paint or
gelcoat. A high energy,
reactive
surface will easily interact with the water molecules and
create a sheeting effect. This surface is called
hydrophillic because it likes (reacts readily) and easily
attracts water molecules. On the other hand, low surface
energy paint or gelcoat surfaces are hydrophobic, do
not react easily with water and therefore the water beads up.
Water is simply an easily understandable way to illustrate
the point that low surface energy reduces interaction with
ALL the environment's elements especially the worst one,
ultraviolet radiation. Another way to say it, is that if
the surface is slick or slippery, it is low energy and
non-reactive. That's what you want. Everybody knows this
intuitively by their reaction to seeing water beading on a
car... It's a good thing!
The third
factor (as we mentioned above), is the inclusion of highly
efficient UV absorbers and light stabilizers into the paint
or gelcoat, which are more fullydiscussed here.
Now that
you have a better understanding of what factors are involved
in sun lights UV fading of either paint or fiberglass
gelcoats on your boat or RV, you can more critically
evaluate what you do for longer term protection of your
paint or gelcoat surfaces. For our
solution click here.